Technically, it's stealing from the company.
If it's wide spread, you have a cultural problem and it's best dealt with it immediately with a large scale meeting, addressing the problem in general terms and follow up with enforcement. Typically, you enforce the same way as if someone was taking office supplies or cash from the register. If it's not wide spread, I'd treat it the same as catching someone taking cash out of the register or stealing office supplies. It's helpful if you have rules about using the time clock correctly and/or policies against stealing (unauthorized possession) and/or policies about absences from one's workstation or the taking of breaks.